Voltammetry at a Microdisk Electrode
Application ID: 12877
Voltammetry is modeled at a microelectrode of 10um radius. In this common analytical electrochemistry technique, the potential at a working electrode is swept up and down and the current is recorded. The current-voltage waveform ("voltammogram") gives information about the reactivity and mass transport properties of the analyte.
Microelectrodes are popular in electroanalysis because they provide high current densities with a small quantity of active electrode material. The short diffusion timescales to a microelectrode mean that the steady-state result is accurate and so a Stationary study can be used. The Secondary Current Distribution and Transport of Diluted Species interfaces are used to couple charge and mass transfer with an electrode reaction.
This application was built using the following:Batteries & Fuel Cells Module Corrosion Module Electrochemistry Module Electrodeposition Module
The combination of COMSOL® products required to model your application depends on the physics interfaces that define it. Particular physics interfaces may be common to several products (see the Specification Chart for more details). To determine the right combination of products for your project, you should evaluate all of your needs in light of each product\'s capabilities, consultation with the COMSOL Sales and Support teams, and the use of an evaluation license.